Transition Elements

Molar mass

Adding atomic masses, ready for iron ores

1. Molar mass: from zero

Molar mass

2. How heavy is one mole of ore?

The book's ore table lists Fe2O3, Fe3O4 and FeCO3. To compare their iron, we need the mass of one mole of each.
A mole is a fixed count of particles (Avogadro's number, 6.02 × 10²³).

Pick the right answer

Predict: Fe = 56 and O = 16. What is the mass of one mole of Fe2O3?
  • A. 72 g
  • B. 160 g
  • C. 5 g
Explanation
One mole of Fe2O3 holds 2 Fe and 3 O: 2 × 56 + 3 × 16 = 112 + 48 = 160 g.

3. Molar mass

Molar mass

The sum of atomic masses of the elements forming the molecule or formula unit, measured in grams (g/mol).
ElementFeOCH
Atomic mass5616121
Rounded atomic masses used in exam problems
Multiply each atomic mass by the number of its atoms. Then add.

4. Worked example: hematite

M(Fe2O3) = 2 × 56 + 3 × 16 = 112 + 48 = 160\ g/mol
Fe₂O₃: 2 Fe atoms, 3 O atoms
Limonite has water of crystallization. The dot means: add the water's mass too.
Show limonite
M(2Fe2O3*3H2O) = 2 × 160 + 3 × 18 = 374\ g/mol
Each H2O is 2 × 1 + 16 = 18. The numbers in front multiply the whole unit.

5. Build an iron oxide

Set the number of Fe and O atoms. Try FeO, Fe3O4 and Fe2O3.

Fe atoms 1

O atoms 1

Mass of Fe 56 g

Molar mass 72 g/mol

6. Your turn: siderite and CO₂

Fill in the blanks

Siderite, FeCO3: molar mass = _____ g/mol (Fe = 56, C = 12, O = 16).
Explanation
56 + 12 + 3 × 16 = 116 g/mol.

Pick the right answer

Coke burns to CO2 in the blast furnace. What is the molar mass of CO2?
  • A. 28 g/mol
  • B. 30 g/mol
  • C. 44 g/mol
  • D. 88 g/mol
Explanation
CO2 has one C and two O: 12 + 2 × 16 = 44 g/mol.

7. Summary

  • Molar mass = sum of the atomic masses in the formula, in g/mol.
  • A subscript multiplies the atom, or the bracketed group, just before it.
  • In a hydrate, add the mass of the water of crystallization.
Back to the hook: can you explain why one mole of Fe2O3 has a mass of 160 g?
Reveal
Fe2O3 has 2 Fe atoms and 3 O atoms: 2 × 56 + 3 × 16 = 112 + 48 = 160 g/mol, so one mole has a mass of 160 g.

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