Transition Elements

Important iron ores

Hematite, limonite, magnetite and siderite

1. Iron ores and extraction of iron

Important iron ores

2. Which one does the magnet pick?

Iron ores are not all the same. They come in different colours.

Pick the right answer

Predict: the four ores are crushed and mixed. A magnet passes over the pile. Which ore sticks to it?
  • A. The blood-red ore
  • B. The black ore
  • C. The yellow ore
Explanation
The black ore is magnetite, the ore with magnetic properties, so it sticks to the magnet. Colour alone does not make a rock magnetic: the blood-red and yellow ores do not have magnetic properties.

3. 1) Hematite

OreHematite
Chemical nameIron III oxide
Chemical formulaFe2O3
PropertiesBlood red colour; more easily reduced
Iron %50-60
Place of depositsOasis area (Western Desert)
In iron III oxide, iron has oxidation state +3.
"Easily reduced" means the oxide easily loses its oxygen to give iron.

4. 2) Limonite

OreLimonite
Chemical nameHydrated iron III oxide
Chemical formula2Fe2O3.3H2O
PropertiesYellow hydrated oxide; easily reduced
Iron %20-60
Place of depositsOasis area
Same iron III oxide as hematite, plus water of crystallization: 3 H2O for every 2 Fe2O3.

True or false?

Limonite has no water in it.
Explanation
Limonite does contain water: the .3H2O in 2Fe2O3.3H2O is water of crystallization, so limonite is a hydrated iron III oxide.

5. 3) Magnetite

OreMagnetite
Chemical nameMagnetic iron oxide
Chemical formulaFe3O4
PropertiesBlack ore having magnetic properties
Iron %45-70
Place of depositsEastern Desert
This is the ore the magnet picked out in the hook.

True or false?

Magnetite's formula is Fe2O3.
Explanation
Fe2O3 is the formula of hematite. Magnetite, the magnetic iron oxide, is Fe3O4.

6. 4) Siderite

OreSiderite
Chemical nameIron II carbonate
Chemical formulaFeCO3
PropertiesYellowish grey colour; easily reduced
Iron %30-42
Place of depositsnot given in the book
Siderite is the odd one out: a carbonate, not an oxide. Here iron has oxidation state +2.

7. All four together

Orelowest (%)highest (%)
Hematite5060
Limonite2060
Magnetite4570
Siderite3042
Iron % range of each ore (book table, p.16)

Match the pairs

Match each ore to its formula.
  • Hematite
  • Limonite
  • Magnetite
  • Siderite

8. Identify the ore

Pick the right answer

A geologist finds a black ore in the Eastern Desert. A magnet attracts it. What is its formula?
  • A. Fe2O3
  • B. Fe3O4
  • C. FeCO3
  • D. 2Fe2O3.3H2O
Explanation
A black ore from the Eastern Desert that a magnet attracts is magnetite, magnetic iron oxide: Fe3O4. Hematite (Fe2O3) is blood red, limonite (2Fe2O3.3H2O) is yellow and siderite (FeCO3) is yellowish grey.

True or false?

Siderite is an iron oxide, like the other three ores.
Explanation
Of the four ores, siderite is the carbonate one: its formula, FeCO3, contains the carbonate group CO3.

9. Sort the clues

Sort into groups

Sort each clue to its ore.

Blood red colourFormula with a water partYellow colourYellowish grey colourFound in the Eastern DesertContains the carbonate group

10. Summary

OreFormulaKey clueIron %
HematiteFe2O3blood red; Oasis area (Western Desert)50-60
Limonite2Fe2O3.3H2Oyellow, hydrated; Oasis area20-60
MagnetiteFe3O4black, magnetic; Eastern Desert45-70
SideriteFeCO3yellowish grey, a carbonate30-42
Can you explain why siderite is the odd one out?

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