Transition Elements

Orbitals

The five orbitals of the d sublevel

1. Orbitals: from zero

Orbitals

2. Why five?

Ch.1 fills 'the five orbitals of 3d' one electron at a time. Why five, and what is an orbital?
A d sublevel holds up to 10 electrons. One orbital holds at most 2. Predict:

Pick the right answer

How many orbitals does the d sublevel have?
  • A. 5
  • B. 10
  • C. 2
Explanation
The d sublevel holds up to 10 electrons, and one orbital holds at most 2. So d has 10 ÷ 2 = 5 orbitals.

3. An orbital is a region, not a path

Orbital

The region of space around the nucleus in which the electron is most likely to be found.
An s orbital. The dots show where the electron is likely to be: the denser, the more likely.

4. Orbitals in each sublevel

Each box is one orbital. Each orbital holds at most 2 electrons.
↑↓
s
↑↓↑↓↑↓
p
↑↓↑↓↑↓↑↓↑↓
d
Full sublevels: s has 1 orbital (2 electrons), p has 3 (6), d has 5 (10)
gatheredmaximum electrons in a sublevel\\ = 2 × number of orbitalsgathered

5. Count the orbitals

Pick the right answer

The f sublevel holds up to 14 electrons. How many orbitals does it have?
  • A. 7
  • B. 14
  • C. 4
  • D. 28
Explanation
The f sublevel holds up to 14 electrons, 2 per orbital, so it has 14 ÷ 2 = 7 orbitals.

True or false?

An orbital is the circular path an electron follows around the nucleus.
Explanation
Orbital = the region of space around the nucleus where the electron is most likely to be found.

6. Summary

  • An orbital is a region where the electron is most likely to be found, not a path.
  • Orbitals: s 1, p 3, d 5, f 7.
  • At most 2 electrons per orbital, so d holds 5 × 2 = 10.
Can you explain why the 3d sublevel can hold 10 electrons?
Reveal
↑↓↑↓↑↓↑↓↑↓
3d
A full 3d sublevel: 5 orbitals, 2 electrons each
The 3d sublevel has 5 orbitals, and each orbital holds at most 2 electrons: 5 × 2 = 10.

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