Transition Elements

Energy sublevels (s, p, d, f)

Why the d block has ten columns

1. Energy sublevels (s, p, d, f): from zero

Energy sublevels (s, p, d, f)

2. Ten columns in the middle

The middle block of the periodic table has exactly 10 columns. Why 10, and not 8 or 18?

Element table

d-block

The middle block: 10 columns (Ch.1 p.3)

Pick the right answer

Predict: why 10 columns?
  • A. Because only 10 such elements are known
  • B. Because the sublevel filled there holds up to 10 electrons
  • C. Because each period has 10 elements
الشرح
In the middle block, the d sublevel is being filled, and a d sublevel holds up to 10 electrons: one column for each electron.

3. Levels are divided into sublevels

Energy sublevels

The parts that a main energy level is divided into: s, p, d and f.
Main levelnSublevelsMaximum electrons
K11s2
L22s, 2p8
M33s, 3p, 3d18
N44s, 4p, 4d, 4f32
Number of sublevels = n. Each sublevel holds at most: s 2, p 6, d 10, f 14.

4. Open a level

Choose a main level. See which sublevels it has.

Main energy level (n) 3

M (n = 3): 3s, 3p, 3d → 2 + 6 + 10 = 18 electrons

Sublevels 3

Maximum electrons (2n²) 18

Add up the sublevels: you get the 2n² of the level.

5. Which sublevels exist?

Fill in the blanks

The N level (n = 4) has _____ sublevels. The one that can hold 14 electrons is _____.
الشرح
N has 4s, 4p, 4d and 4f. The 4f sublevel holds up to 14 electrons.

Pick the right answer

Which sublevel does NOT exist?
  • A. 2d
  • B. 4f
  • C. 3d
  • D. 2p
الشرح
2d does not exist: level 2 has two sublevels, 2s and 2p, and the d sublevel first appears at n = 3. 2p, 3d and 4f exist.

6. Summary

  • Main level n has n sublevels: 1s; 2s 2p; 3s 3p 3d; 4s 4p 4d 4f.
  • Maximum electrons: s 2, p 6, d 10, f 14.
  • The d sublevel first appears at n = 3 (3d).
Can you explain why there is a 3d sublevel but no 2d?
Reveal
Main levelnSublevels
L22s, 2p
M33s, 3p, 3d
Level n has n sublevels. Level 2 has only 2s and 2p, so there is no 2d. The d sublevel first appears at n = 3 (3d).

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